Man’s use of charcoal extends back as far as human history itself. It was first used more than 30,000 years ago to make some of the earliest cave paintings. Much later, charcoal played an important role in what might be considered mankind’s first technology, the smelting and working of metals. In more recent times, charcoal has remained a technologically important material, primarily as a result of its adsorptive properties. The use of activated charcoal in gas masks during World War I saved many thousands of lives, and today charcoal is used on an enormous scale for the purification of air and water. From a scientific perspective, charcoal is also of great interest since we are beginning to achieve a detailed picture of its atomic structure for the first time. In this article I want to look at charcoal from the point of view of art, technology and science.
Historically, production of wood charcoal in districts where there is an abundance of wood dates back to a very ancient period, and generally consists of piling billets of wood on their ends so as to form a conical pile, openings being left at the bottom to admit air, with a central shaft to serve as a flue. The whole pile is covered with turf or moistened clay. The firing is begun at the bottom of the flue, and gradually spreads outwards and upwards. The success of the operation depends upon the rate of the combustion. Under average conditions, 100 parts of wood yield about 60 parts byvolume, or 25 parts by weight, of charcoal; small-scale production on the spot often yields only about 50%, large-scale was efficient to about 90% even by the seventeenth century. The operation is so delicate that it was generally left to colliers (professional charcoal burners).