Ben, I also think thatch is good and was just mentioning the pros and con. As I said, I'm not sure what I would use, preferably something sustainable.
Anyone building from bamboo should be concerned about it being eaten. The thatch sheets have split bamboo with the grass tied to it. The pieces of split bamboo can be attacked by insects, sometimes within a few weeks. My worry is that these insects will move into the bamboo structure.
The info about ventilation and insulation is all pretty basic, but thanks anyway.