Hi Chris,
I have had this evening discussions with the dutch guy, the general consensus is, remove some of the concrete around the exposed part to provide you with a concave and fill able hole. This will also give you an indication of how deep the porous area is. Looking at the pics, you have at least a 200 mm plus wall thickness i doubt if the porous part is more than a few cm deep. I would use sika water plug with cement to then fill the hole. This is to protect the re-bar, more than prevent leakage. i would be surprised if there is leakage at all.
In my younger day i built concrete water tanks, 100's of the mothers, this was not an uncommon problem.
Getting back to the pool, the water proofing is in the coatings that are applied after the concrete shell is constructed. Looking at the pics, you will want to square up your walls, this being the case, there is 40 mm plus in areas to achieve this.
if you are concerned, add some water proofing ad mixture to the render, Sika carry this product.
Tiles I assume are the finish covering, make sure the tiler uses the small crosses or the mosaics on a back matting. If this does not happen the Khmer tend to butt the tiles together which does no allow grout of any substance between the tiles.
This results in the grout falling out.
Then use a grout that is recommended for pools.
Back in Oz the majority of the pools have a marble- cement render finish, it has some acrylic glue component, sets like the proverbial shit to the blanket and achieves waterproofing.
I hope this helps
cheers.